If you would like to learn Adobe GoLive CS then watching these video tutorials is the easiest way.
To view the Free Tutorials listed below, you must have QuickTime installed.
The Document Window
The Toolbar
The Inspector
The Library Palette
The History Palette
Other Palettes & Windows
Saving Custom Workspaces
The Tools & Menu
Basic Tools
Smart Object Tools
Form Tools
Head Elements
Frame Tools
Site & Diagram Items
QuickTime & SMIL Tools
Object Palette Options
The Menu System Pt.1
The Menu System Pt.2
The Menu System Pt.3
Formatting Text
Bringing in Text
Formatting Paragraphs
HTML Styles Pt.1
HTML Styles Pt.2
Working with Fonts & Lists
Font Set Editor
Spell Checker
Find & Replace
Find & Spell Checker Preferences
Font & Encoding Preferences
Images
Working with Images
Manipulating Images
Alternative Text Labels
Aligning Text & Images
Background Images
Image Maps Pt.1
Image Maps Pt.2
Rollovers Pt.1
Rollovers Pt.2
Rollovers Pt.3
Linking
Text Links
Image Links
Linking Sites
Email Links
Working with Anchors
Link Colors
Source Editing
The Source Editor
Formatting
Head Elements
Syntax Checking Pt.1
Syntax Checking Pt.2
Site Syntax Checking
Document Types (XHTML)
The Outline Editor
Source Code Preferences
Style Sheets (CSS)
Working with Style
Embedded Style Pt.1
Embedded Style Pt.2
Linking to Style Sheets
Managing Style Sheets
Working With Classes
ID Styles
Working with the CSS Editor
Managing Site Style
Form Basics
Setting up Forms
Text Fields & Labels
Text Areas
Selection Boxes
Check Box
Radio Buttons
Hidden Fields
Submit & Reset Buttons
More on Form Submission
Setting the Tab Order
CSS & Form Elements
Form Field Inventory
Working with Color
The Color Palette
The Swatches Palette
Site Colors
Frames
The Basics of Frames
Modifying Frame Sets
Modifying Frames
Linking & More
GoLive Actions
Actions & JavaScript
Types of Actions
Mouse Events
Form Validation
Optimized & Modular
Image Actions
Advanced Page Layout (DHTML)
Layout Grids
More on Layout Grids
Layer Palette & Layers
Working with Floating Boxes
Grids to Tables & Back Again
QuickTime and GoLive CS
QuickTime Tag Options, P1
QuickTime Tag Options, P2
Video Track Editing
The Track Timeline Editor
Working with QuickTime Tracks
Other Rich Media
Working with Flash
Java Applets
Real System Media
Windows Media (PC)
Generic Plug-ins and ActiveX
IPIX 360 Source Code
Web Pages to PDF
Adobe PDF Preferences
Adobe Integration
Smart Objects
Working with Smart Objects
Smart Photoshop Integration
Smart Illustrator Integration
Site Assets
Site Assets
Snippets
Page Templates
Creating Page Templates
Creating Stationary
Creating Site Components
Site Management
Site Planning
In & Out Links Palette
Link Management
Fixing Site Errors
Cleaning Up Sites
Site Preferences
Site Settings
Site Options - Publish States
Exporting a Site
More Preferences
General Preferences
More General Preferences
Browser Preferences
Other Preferences
Site Publishing (PC)
Working With FTP
Uploading Content
Remote Editing (Syncing)
Site Publishing (Mac)
Working With FTP
Uploading Content
Remote Editing (Syncing)
Collaborative Authoring
Co-Authoring
Creating Co-Author Sections
Creating Templates Pt.1
Creating Templates Pt.2
Generating & Publishing Pages
Version Cue (GoLive Import)
Version Cue Admin
Working with Version Cue